Course syllabus
Previous knowledge requirements:
General chemistry, inorganic chemistry, organic chemistry and physical chemistry at the BSc level
Learning goals:
- Students should be able to explain the principles of ligand field theory and apply it to predict the electronic structure and properties of coordination complexes.
- Students should be able to identify different coordination geometries and understand the factors that influence the geometry of coordination complexes.
- Students should understand the nature of metal-ligand bonding, including σ-bonding, π-bonding, and back-bonding, and be able to explain how different ligands affect the strength and nature of metal-ligand bonds.
- Students should understand how magnetic properties are related to the electronic structure of coordination complexes
- Students should be able to chose physical methods (UV-Vis, IR, NMR, SCXRD, EPR, magnetometry etc) for investigating coordination chemistry problems.
- Students should be able to explain the mechanisms of common reactions involving coordination complexes, such as substitution, redox, and photochemical reactions.
- Students should understand the role of metal ions in biological systems, and be able to explain the coordination chemistry involved in biological processes.
- Students should understand the applications of coordination chemistry in catalysis and be able to explain the underlying coordination chemistry principles involved.
- Students should be aware of current research topics and trends in coordination chemistry.
Contents:
- Principles of ligand field theory
- Application of ligand field theory to predict electronic structure and properties
- Correlation between ligand field strength and spectroscopic properties
- Identification of different coordination geometries
- Factors influencing coordination geometry
- Structural and spectroscopic characterization techniques
- σ-bonding, π-bonding, and back-bonding
- Ligand effects on metal-ligand bond strength
- M;agnetic properties and electronic structure
- Application of EPR spectroscopy
- Selection of physical methods for investigating coordination chemistry problems
- Advanced techniques such as SCXRD for structural elucidation
- Mechanisms of substitution, redox, and photochemical reactions
- Kinetic and thermodynamic considerations in coordination chemistry reactions
- Role of metal ions in biological systems
- Coordination chemistry in metalloenzymes and metalloproteins
- Application of coordination chemistry principles in understanding biological processes
- Catalytic applications of coordination complexes in various reactions
- Mechanistic insights into catalytic processes
- Design principles for catalyst development based on coordination chemistry
- Exploration of modern research topics in coordination chemistry
Course summary:
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